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Hazardous Substances - Art. [3], Mancozeb is listed under FRAC code M:03 The "M:" refers to Chemicals with Multi-Site Activity. Biocidal Products Committee opinions on active substance approval, National authorisation and mutual recognition, Understanding the Waste Framework Directive, Tools to prepare and submit SCIP notifications, List of substances subject to the POPs Regulation, Draft recommendation for inclusion in the Authorisation List and consultation, Submitted restrictions under consideration, Harmonised classification and labelling targeted consultations, Consultations on ECHA Executive Director’s requests, PACT - Public Activities Coordination Tool, Information on Candidate List substances in articles, Candidate List of substances of very high concern for Authorisation, Registry of restriction intentions until outcome, Registry of SVHC intentions until outcome, Table of harmonised entries in Annex VI to CLP, Occupational exposure limits - Activity list, Harmonised classification and labelling (RAC), Candidate list of substances of very high concern for authorisation, Annex III: criteria for 1 - 10 tonne registered substances, Harmonised classification and labelling - previous consultation, CAD - Chemical Agents Directive, Art. Close Find out more on how we use cookies. 92/85/EEC on Pregnant Workers, 28 November 1992 (updated by table 3 of Annex VI to CLP, 5 Oct 2018), EU. This database contains substances that have been assigned hazard property (HP) waste codes 1-15, as defined in terms of the hazard class & category, hazard (H) statement, and/or concentration limits provided in Annex III of the Waste Framework Directive (2008/98/EC). This information has not been reviewed or verified by ECHA, and may change without prior notice. The molecular structure is based on structures generated from information available in ECHA’s databases. In that case, the ATP (Adaptation to Technical Progress) number is displayed. (5)To prevent anthrax and erythema of kidney beans, use 400-700 times liquid spray, and spray 2-3 times. Make a slurry with the mancozeb. Pure Mancozeb is white powder,Industrial products are pale white or pale yellow powder,smell like rotten egg,insoluble in water,Insoluble in most organic solvents,But it dissolves in pyridine.Unstable to light, heat and moisture,Carbon disulfide easily decomposes,When alkaline or copper, mercury and other substances easily decompose carbon disulfide to reduce the effect,volatile little.The so-called … As long as the product is stored in its unopened and undamaged original containers in well-ventilated places, its biological activity will remain stable for 2 years (2). More information about Classification and Labelling is available in the Regulations section of ECHA website. Mancozeb has a low mammalian toxicity by has been associated with adverse reproduction/development effects. A two-year feeding study on rats indicated that 6.25 mg/kg of maneb in the diet is the no observable effect level (NOEL) for rats. The date of the last update corresponds to the publication date of the InfoCard and not necessarily to the date in which the update occurred in the source data. Although widely used on food crops to treat fungal disease, it has detrimental effects on the nervous system and should be used with caution. Mancozeb is quite potent and one gallon is enough to treat 1000 square feet. It is also unstable in acidic conditions (7).

215–540–4, is covered by three harmonisations: 005–011–00–4; 005–011–01–1 and 005–011–02–9), CLH information cannot be displayed in the InfoCard as the difference between the CLH classifications requires manual interpretation or verification. Suspensions of mancozeb dust in the air can ignite or explode (19). Annex of Approved Active Substances for Plant Protection Products, Protection of Pregnant and Breastfeeding Workers Directive, Annex I+II, Workplace Signs - minimum requirements & signs on containers and pipes, Waste Framework Directive, Annex III - Waste - Hazardous Properties, Fertiliser Regulation- Annex I, E.3 (chelating and complexing agents), Substances of very high concern identification, Recommendation for the Authorisation List, Getting started with EU chemicals legislation, Classification of substances and mixtures, Harmonised classification and labelling (CLH). The database represents a non-exhaustive list of such substances based on: 1) agents of risk groups 3 and 4 under Directive 2000/54/EC; 2) Table 3 of Annex VI to the CLP Regulation; 3) and Annex I of Directive 2004/37/EC.

The ‘Hazard classification’ and labelling section uses the signal word, pictogram(s) and hazard statements of the substance under the harmonised classification and labelling (CLH) as its primary source of information. Hazard statements were adapted to improve readability and may not correspond textually to the hazard statements codes description in the European Union Specific Hazard Statements (EUH) or the. This can be a commercial sprayer cleaner or dish soap. The EC or list number is the primary substance identifier used by ECHA. Ferbam and Ziram have the same organic moiety and the difference is in the metallic ion. [2], Mancozeb reacts with, and inactivates, the sulfhydryl groups of amino acids and enzymes within fungal cells, resulting in disruption of lipid metabolism, respiration, and production of adenosine triphosphate. It is poisonous to fish and cannot pollute water. Note that for readability purposes, only the pictograms, signal words and hazard statements referred in more than 5% of the notifications under CLP are displayed. Mixing Rate for all uses: 50g per 10L of water. [4], A major toxicological concern is ethylenethiourea (ETU), an industrial contaminant and a breakdown product of mancozeb and other EBDC pesticides. Note that this list is not exhaustive.

2(b)(i), Directive 98/24/EC on Protection of Workers from Chemical Agent-related Risks, 5 May 1998 (Table 3 of Annex VI to CLP, as amended), EU. Apply the mancozeb solution with the sprayer. If a substance is classified under multiple CLH entries, a link to the C&L Inventory is provided to allow users to view CLH information associated with the substance and no text is automatically generated for the InfoCard. Mancozeb is a fungicide that also works as an insecticide. Fungicides like chlorothalonil, mancozeb, and copper can be applied to prevent late blight infection in tomatoes. Measure the area you plan to treat. Non-Exhaustive List of Banned Substances, Directive 94/33/EC on Young People at Work, 20 August 1994, as amended by Dir 2014/27/EU, March 5, 2014 (Based on Table 3 of Annex VI to CLP, inter alia), EU. Boron (LD50: 560 mg/kg) Boron is used by organic farmers as a fertiliser. If available, additional information on classification and labelling (C&L) is derived from REACH registration dossiers submitted by industry. So in some situations it is easier to determine the residue of only one fungicide. Research shows that mancozeb is rapidly absorbed into the body from the gastrointestinal tract, distributed to various target organs and almost completely excreted in 96 hours. A prioritisation hierarchy means that data is taken from harmonised C&L data and regulatory lists first, then REACH registrations and finally from CLP notifications. Occupational exposure limit (OEL) values are derived within two legal frameworks that form an integral part of the EU’s mechanism for protecting the health of workers. If you have questions or suggestions,please leave us a message,your inquiry will be replied within 12 hours. Warning! It is sold under the commercial names of Dithane, Manzeb, Manzane and Nemispot. If no EU harmonised classification and labelling exists and the substance was not registered under REACH, information derived from classification and labelling (C&L) notifications to ECHA under CLP Regulation is displayed under this section. Substances indicated, in 2009, as being intended to be registered by at least one company in the EEA.

When information is available in all sources, the first two are displayed as a priority.

It has a low aqueous solubility, is quite volatile and not expected to leach to groundwater. Substances according to Hazardous Waste Properties: Annex III, Directive 2008/98/EC, 22 November 2008, amended by Directive 2018/851/EU, 14 June 2018, Registration, Evaluation, Authorisation and Restriction of Chemicals, Chemical Agents Directive and Carcinogens or Mutagens Directive, PPP - Plant Protection Products Regulation, Protection of Pregnant and Breastfeeding Workers Directive, Safety and/or Health Signs at Work Directive, mancozeb (ISO); manganese ethylenebis(dithiocarbamate) (polymeric) complex with zinc salt, Other, CAD - Chemical Agents Directive, Art.

It is sold under the commercial names of Dithane, Manzeb, Manzane and Nemispot. While it is relatively stable and noncorrosive under normal, dry storage conditions, it is decomposed at high temperatures by moisture and by acid. (4)Control cabbage, cabbage downy mildew, celery spot disease, with 500 to 600 times of liquid spray, spray 3-5 times.

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